郝健的博客

 1.    Novel blue light emitting anthracene derivatives, under preparation.

郝 健(Jian Hao)   工学博士、教授、博导

         1986-1994：上海有机化学研究所，研究实习员、助理研究员 
         1994-1995：访问学者,Univ of Florida化学系(Prof W.R.Dolbier, Jr.) 
         1996-1999：博士生，日本冈山大学 (Prof Kenji Uneyama) 
         1999-2000：博士后，东京工业大学 (Prof. Koichi Mikami) 
         2001：Visiting Assistant Prof，香港科技大学 (吴云东院士) 
         2002-至今：教授，上海大学化学系；2006-至今：博导，上海大学材料学专业

         2005-至今：上海大学科技处副处长

         美国化学会(ACS)会员/ Fluorine Division

         办公室电话、传真（Office Tel & Fax）：021-66133380

         邮箱地址（Email）：jhao@shu.edu.cn 

         目前研究领域：含氟杂环化学、含氟功能小分子与OLED材料、有机小分子催化。

1.      含氟b-氨基酸及其衍生物的合成进展, 彭荣达，郝健, 有机化学，2005, 25, 485-495.

2.     Grignard Cyclization Reaction of Fluorinated N-Aryl I_midoyl Chlorides. A Novel and Facile Access to  the 2-Fluoroalkyl Indoles, Ge, F.; Wang, Z.; Wan, W.; Hao, J.* Synlett, 2007, 447-450.

3.     One-pot synthesis of 2-trifluoromethyl and 2-difluoromethyl substituted benzo-1,3-diazoles, Ge,F.; Wang, Z.; Wan, W.; Lu, W.; Hao, J.* Tetrahedron Lett. 2007，48, 3251-3254.

4.     5,5,5-Trifluoro-N-(4-fluorophenyl)-4-hydroxypentana__mide, Wan, W.; Ma, G.; Yuan, Z.; Li, M.; Hao, J.*  Acta Cryst. 2007, E63, o1685–o1686.

5.     Fluorinated N-[2-(haloalkyl)phenyl]i_midoyl chloride, a key intermediate for the synthesis of2-fluoroalkyl substituted indole derivatives via Grignard cyclization process, Wang, Z.; Ge, F.; Wan, W.; Jiang,H.; Hao, J.* J. Fluorine Chem. 2007, 128, 1143-1152.

6.     3-Chloro-1,1,1-trifluoro-3-(triphenylphosphoranylidene)propan-2-one, Wang, Z.; Jiang, H.; Wan, W.; Ge,F.; Hao, J.* Acta Cryst. 2007, E63, o3152.

7.     Recent Progress in One-pot Synthesis of Fluorinated Building Blocks, Ren, X.; Wan, W.; Jiang, H.; Hao, J.* Mini-Rev. in Org. Chem. 2007, 4, 330-337.

8.     One-pot Cyclization of 2-Aminophenethyl Alcohols: A Novel and Direct Approach to the Synthesis of N-Acyl Indolines, Wang, Z.; Wan, W.; Jiang, H.; Hao, J.* J. Org. Chem. 2007, 72, 9364-9367.

9.     14-Androsta-5,15-dien-3-ol-17-one, Zheng, C.; Yao, S.; Wan, W.; Hao, J.* Acta Cryst. 2007, E63, o2651.

10.   Fluoroalkyl Substituted (Z)-Dehydro α-Amino Ester as a Building Block for the Fluorine-containing Cyclopropyl α-Amino Esters and Dihydrooxazole, Wan, W.; Gao, Y.; Jiang, H.; Hao, J.* J. Fluorine Chem. 2008, 129, 510-514.

11.  Synthesis and _characterization of triphenylene derivatives containing two terminal functional grous atthe periphery, Wan, W.*; Wang, P.; Jiang, H.; Hao, J.  J. Mol Cryst Liq Cryst. 2008, 482, 42-56.

12.  Synthesis and _characterisation of nematic liquid crystalscontaining a trans-decalin ring, Wan, W.*  Yang, C.; Jiang, H.; Wang, J. Hao, J. Liq. Cryst. 2008, 35, 665-673.

13.  Ethyl 2-phenyl-5-trifluoromethyl-1,3-thiazole-4-carboxylate, Jiang, H.; Wan, W.; Shao, M.; Hao, J.* Acta Cryst. 2008, E64, o2004.

14.  Concise Synthesis of ω-Fluoroalkylated Ketoesters. A Building Block for the Synthesis of 6-, 7-, and8-Membered Fluoroalkyl Substituted 1,2-Diaza-3-One Heterocycles, Wan, W.; Hou, J.;Jiang, H.; Wang,Y.; Zhu, S.; Deng, H.; Hao, J.* Tetrahedron, 2009,65，4214-4219.

15.  Recent Progress on the Synthesis of Trifluoromethylated Heterocyclic Compounds Based on ethyl 4,4,4-trifluoroacetoacetate and its Derivatives, Zhu, S.Z.; Song, L.P.; Jin, G.F; Dai, B.F.;Hao, J. Current Org. Chem. 2009, 13, 1015-1027.

16.  Reductive Amination/Cyclization of ω-Trifluoromethyl Ketoesters. Synthesis of Trifluoromethylated δ-Amino Alcohols and Lactams, Eur. J. Org. Chem., 2010, 9, 1778-1786. http://www3.interscience.wiley.com/journal/123278435/abstract

17.  p-TsOH Promoted Fischer Indole Synthesis of Multi-Substituted 2-Trifluoromethyl Indole Derivatives,  Tetrahedron, 2010, 66, 2746-2751.http://dx.doi.org/10.1016/j.tet.2010.01.080

18. Bromotriphenylphosphonium Salt Promoted Tandem One-Pot Cyclization to the Optically Active 2-Aryl-1,3-Oxazolines,2010, article, under revision (EJOC).

19. Novel C-9 Fluorenyl Substituted Anthracenes for Blue Light Emitting OLED，2010，submitted.